Opis: Monitoring Polymerization Reactions - Alina M. Alb, Wayne F. Reed

Offers new strategies to optimize polymer reactions With contributions from leading macromolecular scientists and engineers, this book provides a practical guide to polymerization monitoring. It enables laboratory researchers to optimize polymer reactions by providing them with a better understanding of the underlying reaction kinetics and mechanisms. Moreover, it opens the door to improved industrial-scale reactions, including enhanced product quality and reduced harmful emissions. Monitoring Polymerization Reactions begins with a review of the basic elements of polymer reactions and their kinetics, including an overview of stimuli-responsive polymers. Next, it explains why certain polymer and reaction characteristics need to be monitored. The book then explores a variety of practical topics, including: Principles and applications of important polymer characterization tools, such as light scattering, gel permeation chromatography, calorimetry, rheology, and spectroscopy Automatic continuous online monitoring of polymerization (ACOMP) reactions, a flexible platform that enables characterization tools to be employed simultaneously during reactions in order to obtain a complete record of multiple reaction features Modeling of polymerization reactions and numerical approaches Applications that optimize the manufacture of industrially important polymers Throughout the book, the authors provide step-by-step strategies for implementation. In addition, ample use of case studies helps readers understand the benefits of various monitoring strategies and approaches, enabling them to choose the best one to match their needs. As new stimuli-responsive and "intelligent" polymers continue to be developed, the ability to monitor reactions will become increasingly important. With this book as their guide, polymer scientists and engineers can take full advantage of the latest monitoring strategies to optimize reactions in both the lab and the manufacturing plant.Preface ix Introduction xi Contributors xiii SECTION I O VERVIEW OF POLYMERIZAT ION REACTIONS AND KINETICS-1 1 Free Radical and Condensation Polymerizations 3 Matthew Kade and Matthew Tirrell 2 Overview of Controlled/Living Polymerization Methods of Vinyl Monomers 29 Robert T. Mathers, Andrew J. D. Magenau, Kristin Schroder, and Krzysztof Matyjaszewski 3 Stimuli-Responsive Polymers via Controlled Radical Polymerization 45 Joel D. Flores, Brooks A. Abel, DeeDee Smith, and Charles L. McCormick 4 Reactions in Heterogeneous Media: Emulsion, Miniemulsion, Microemulsion, Suspension, and Dispersion Polymerization 59 Radmila Tomovska, Jose C. de la Cal, and Jose M. Asua SECTION 2 Polym erization Characterization and Monitoring Methods 79 5 Polymer Characteristics 81 Wayne F. Reed 6 Infrared (MIR, NIR), Raman, and Other Spectroscopic Methods 107 Alexandre F. Santos, Fabricio M. Silva, Marcelo K. Lenzi, and Jose C. Pinto 7 Calorimetry, Conductivity, Densimetry, and Rheological Measurements 135 Jose R. Leiza and Timothy McKenna 8 Light Scattering 151 Guy C. Berry 9 G PC/SEC as a Key Tool for Assessment of Polymer Quality and Determination of Macromolecular Properties 171 Daniela Held and Peter Kilz 10 Mass Spectroscopy: ESR and NMR Applications to Polymer Characterization and Polymerization Monitoring 201 Zifu Zhu and Alina M. Alb SECTION 3 A utomatic Continuous Online Monitoring of Polymerization Reactions (ACOMP) 229 11 Background and Principles of Automatic Continuous Online Monitoring of Polymerization Reactions (ACOMP) 231 Wayne F. Reed 12 Applications of ACOMP (I) 247 Alina M. Alb 13 Applications of ACOMP (II) 271 Wayne F. Reed 14 Cognate Techniques to ACOMP 295 Michael F. Drenski, Alina M. Alb, and Wayne F. Reed 15 Outlook for Industrial ACOMP 313 Michael F. Drenski and Alex W. Reed SECTION 4 Reactor Control and Design: Batch, Semi-batch, and Continuous Reactors 325 16 Mathematical Modeling of Polymerization Reactors 327 F. Joseph Schork 17 Design and Operation of Polymerization Reactors 345 F. Joseph Schork 18 Optimization of the Particle Size in Emulsion Polymerization 363 Joseph Zeaiter and Jose A. Romagnoli SECTION 5 Industrial Applications 381 19 Water-Soluble Free Radical Addition Polymerizations 383 Wesley L. Whipple and Hua Zheng 20 Protein Aggregation in Pharmaceutical Biotechnology 395 Mark L. Brader 21 Rubbers and Elastomers 409 Jorge Soto 22 Polymers from Natural Products 427 Dimitrios Samios, Aline Nicolau, and Miriam B. Roza Index 451

Szczegóły: Monitoring Polymerization Reactions - Alina M. Alb, Wayne F. Reed

Tytuł: Monitoring Polymerization Reactions
Autor: Alina M. Alb, Wayne F. Reed
Producent: Blackwell Science
ISBN: 9780470917381
Rok produkcji: 2014
Ilość stron: 488
Oprawa: Twarda
Waga: 1.35 kg

Recenzje: Monitoring Polymerization Reactions - Alina M. Alb, Wayne F. Reed