Opis: Surface Phenomena in the Structural and Mechanical Behaviour of Solid Polymers - N. F. Bakeev, L. Volynskii

Surface Phenomena in the Structural and Mechanical Behaviour of Solid Polymers explores the role of various surface phenomena in the structural and mechanical behaviour of amorphous and semicrystalline polymers. This book: * Discusses the development of the interfacial surface in the deformation of polymers * Examines the healing of interfacial surfaces in polymers * Inspects the structure and properties of polymers in thin films and surface layers * Evaluates the mechanism of inelastic deformation in glassy amorphous polymers * Investigates strain softening and the phenomena taking place upon deformation of polymers in active liquid media * Covers the Rehbinder effect, or the adsorption reduction of the strength of solids * Describes the properties of polymers in environmental or solvent crazing * Analyses the interaction of the highly developed surface of crazed polymers with diverse low- and high-molecular mass components * Addresses the instability and self-organisation of surface layers in polymers and diverse polymer systems * Presents theoretical speculations concerning the structurally mechanical behaviour of 'a rigid coating on a soft substratum' (RCSS) systems * Assesses the stress-strain properties of the thin surface layers of polymers and the nanometric coatings deposited on their surfaces * Highlights the efficacy of the approaches developed for RCSS systems for the analysis and description of natural phenomena * Details the applied aspects of surface phenomena in the structurally mechanical behaviour of polymers Thus, Surface Phenomena in the Structural and Mechanical Behaviour of Solid Polymers provides a useful framework for the development of new and innovative polymer-based materials.Development of the interfacial surface in deformation of polymers The method for visualisation of structural rearrangements taking place during the variation of the surface area of deformed polymers Visualisation of structural rearrangements accompanying the development of the interfacial surface in deformation of rubbery polymers Visualisation of structural rearrangements taking place during annealing of amorphous polymers oriented above the glass transition temperature Rolling of glassy polycarbonate Structural rearrangement in the deformed polymer in the conditions of isometric heating Healing of the interfacial surface in polymer systems Healing of the interfacial surfaces in rubbery polymers Healing of the interfacial surface in glassy polymers Heterophase healing of polymer interfaces Heterochemical healing of the polymer-polymer interfaces Monolithization of powders Healing of the interfaces produced upon fracture of glassy polymers Healing of the interfacial surface in deformed polymers Special features of the structure and properties of surface layers and thin (nanometric) films of glassy polymers Measurement of the glass transition temperature of amorphous glassy polymers in thin films and thin surface layers Glass transition temperature of thin films of glassy polymers deposited on solid substrates The glass transition temperature of free-standing thin films of glassy polymers Measurement of the glass transition temperature and molecular mobility in surface layers of bulk glassy polymers Interaction of metal nanoparticles with polymer surfaces Possible reasons for the decrease of the glass transition temperature in thin films and surface layers of amorphous polymers Role of surface phenomena in shear yielding of glassy polymers Thermal ageing of polymer glasses The main features of the effect of thermal ageing on the properties of glassy polymers Physical ageing and the structure of glassy polymers Molecular mechanism of thermal ageing of glassy polymers Effect of mechanical action on the process of physical ageing of polymer glasses Properties of glassy polymers subjected to mechanical effects The spatial inhomogeneity of deformation of polymer glasses Structure of shear bands formed during deformation of glassy polymers The nature of structural-mechanical anomalies in the properties of deformed glassy polymers Role of surface phenomena in the strain softening of glassy and semicrystalline polymers Strain softening of polymer systems, taking place without the formation of porosity Strain softening of glassy polymers Factors causing force softening of glassy polymers during crazing Strain softening of semicrystalline polymers Mechanism of strain softening of semicrystalline polymers Role of surface phenomena in deformation of polymers in active liquid media What is the adsorption-active medium? Structural special features of deformation of polymers in adsorption-active media Crazing in liquid media - manifestation of the Rehbinder effect in polymers Mechanism of the formation of the unique structure of crazes Crazing dynamics of polymers in liquid media Main factors determining the dynamics of crazing of the polymer in the AAM The multiplicity factor of the number of sites of localised plastic deformation Relationship of the crazing dynamics of polymers in liquid media with the fine structure of crazes Crazing mechanism of polymers in liquid media Delocalized crazing of the polymers in liquid media The structure and properties of crazed polymers Structural-mechanical aspects of deformation of crazed polymers Thermomechanical properties of crazed polymers Colloidal swelling Adsorption properties of the crazed polymers Multiphase nanodispersed systems based on crazed polymers Interaction of low-molecular substances with the highly developed surface of the crazed polymer Polymer-polymer nanomixtures based on crazed polymers Crazing as a method of producing nanosized porosity in polymers Special features of production of polymer-polymer nanocomposite by polymerisation in situ in a crazed polymer matrix Direct addition of the second polymer component to the crazed polymer matrix Instability and self-organisation of polymer surfaces Special features of the development of interfacial surfaces during the flow of polymer melts and solutions Loss of stability and dispersion in flow and during phase separation in polymer systems Inhomogeneous swelling of polymers Electrodynamic and thermomechanical instability of polymer surfaces Polymers with thin rigid coatings Mechanism of the formation of the regular microrelief Regular fragmentation of the coating Surface structure formation in polymers with a chemically modified surface Polymer films with nanometric coatings - 'rigid coating on a soft substratum' systems Evaluation of the structural and mechanical properties of nanometric surface layers Physical fundamentals of the method for evaluating the stress-strain properties of surface layers and nanometric coatings deposited on polymer films Modification of polymer surfaces Evaluation of the stress-strain properties of coatings deposited on polymer surfaces Evaluation of the stress-strain properties of nanometric aluminium coatings Evaluation of the stress-strain properties of nanometric coatings based on noble metals Non-metallic coatings Natural systems constructed on the basis of the 'rigid coating on a soft substratum' principle Examples of 'a rigid coating on a soft substratum' natural systems The Earth - the typical 'a rigid coating on the soft substratum' system Evaluation of the thickness of the Earth's crust Evaluation of the strength and longevity of the Earth's crust Perspectives for the practical application of surface phenomena in solid polymers A new approach to the formation of nanocomposites with a polymer matrix Production of polymer films and fibres capable of influencing the environment Technological aspects of polymer modification by crazing Methods for increasing the efficiency of crazing Producing the transverse microrelief in polymer fibres and films Practical application of polymer films with a regular microrelief

Szczegóły: Surface Phenomena in the Structural and Mechanical Behaviour of Solid Polymers - N. F. Bakeev, L. Volynskii

Tytuł: Surface Phenomena in the Structural and Mechanical Behaviour of Solid Polymers
Autor: N. F. Bakeev, L. Volynskii
Wydawnictwo: Productivity Press Inc
ISBN: 9781498743686
Rok wydania: 2016
Ilość stron: 536
Oprawa: Twarda
Waga: 0.88 kg

Recenzje: Surface Phenomena in the Structural and Mechanical Behaviour of Solid Polymers - N. F. Bakeev, L. Volynskii