Opis: Undergraduate Instrumental Analysis - George Frame, Eileen Skelly Frame, James Robinson

Crucial to research in molecular biology, medicine, geology, food science, materials science, and many other fields, analytical instrumentation is used by many scientists and engineers who are not chemists. Undergraduate Instrumental Analysis, Seventh Edition provides users of analytical instrumentation with an understanding of these instruments, covering all major fields of modern instrumentation. Following the tradition of earlier editions, this text is designed for teaching undergraduates and those with no analytical chemistry background how contemporary analytical instrumentation works, as well as its uses and limitations. Each chapter provides a discussion of the fundamental principles underlying the techniques, descriptions of the instrumentation, and numerous applications. The chapters also contain updated bibliographies and problems, and most have suggested experiments appropriate to the techniques. This completely revised and updated edition covers subjects in more detail, such as a completely revised x-ray chapter, expanded coverage of electroanalytical techniques, and expansion of chromatography and mass spectrometry topics to reflect the predominance of these instruments in laboratories. This includes state-of-the-art sample introduction and mass analyzers, and the latest developments in UPLC and hyphenated techniques. The book also contains new graphics and addresses several new topics: * Ion mobility spectrometry * Time domain NMR (relaxometry) * Electron spin resonance spectroscopy (ESR, EPR) * Forensic science and bioanalytical applications * Microcalorimetry and optical thermal instruments * Laser-induced breakdown spectroscopy (LIBS) This text uniquely combines instrumental analysis with organic spectral interpretation (IR, NMR, and MS). It provides detailed coverage of sampling, sample handling, sample storage, and sample preparation. In addition, the authors have included many instrument manufacturers' websites, which contain extensive resources.Concepts of Instrumental Analytical Chemistry Introduction: What is Analytical Chemistry? Analytical Approach Basic Statistics and Data Handling Sample Preparation Performing the Measurement Assessing the Data Problems Bibliography Introduction to Spectroscopy Interaction Between Electromagnetic Radiation and Matter Atoms and Atomic Spectroscopy Molecules and Molecular Spectroscopy Absorption Laws Methods of Calibration Optical Systems Used in Spectroscopy Spectroscopic Technique and Instrument Nomenclature Suggested experiments Problems Bibliography Magnetic Resonance Spectroscopy Nuclear Magnetic Resonance Spectroscopy Introduction The FTNMR Experiment Chemical Shifts Spin-Spin Coupling Instrumentation Analytical Applications of NMR Hyphenated NMR Techniques NMR Imaging and MRI Time Domain NMR Low-Field, Portable, and Miniature NMR Instruments Limitations of NMR Electron Spin Resonance Spectroscopy Suggested Experiments Problems Spectral Databases Bibliography Infrared, Near-Infrared, and Raman Spectroscopy Absorption of IR Radiation by Molecules IR Instrumentation Sampling Techniques FTIR Microscopy Nondispersive IR Systems Analytical Applications of IR Spectroscopy NIR Spectroscopy Raman Spectroscopy Chemical Imaging Using NIR, IR, and Raman Spectroscopy Suggested Experiments Problems Bibliography Spectral Databases Visible and Ultraviolet Molecular Spectroscopy Introduction Instrumentation UV Absorption Spectra of Molecules UV Spectra and the Structure of Organic Molecules Analytical Applications Accuracy and Precision in UV/Vis Absorption Spectrometry Nephelometry and Turbidimetry Molecular Emission Spectrometry Instrumentation for Luminescence Measurements Analytical Applications of Luminescence Suggested Experiments Problems Bibliography Atomic Absorption Spectrometry Absorption of Radiant Energy by Atoms Instrumentation Atomization Process Interferences in AAS Analytical Applications of AAS Suggested Experiments Problems Appendices Bibliography Atomic Emission Spectroscopy Flame Atomic Emission Spectroscopy Atomic OES Plasma Emission Spectroscopy GD Emission Spectrometry AFS Commercial Atomic Emission Systems Laser-Induced Breakdown Spectroscopy Atomic Emission Literature and Resources Comparison of Atomic Spectroscopic and ICP-MS Techniques Suggested experiments Problems Appendices Bibliography X-Ray Spectroscopy (Contributing authors: Alexander Seyfarth and Eileen Skelly Frame) Origin of X-Ray Spectra X-Ray Fluorescence X-Ray Absorption X-Ray Diffraction X-Ray Emission Commercial X-Ray Instrument Manufacturers Suggested Experiments Problems Appendices Bibliography Mass Spectrometry I: Principles and Instrumentation Principles of MS Instrumentation Ion Mobility Spectrometry Problems Bibliography Mass Spectrometry II: Spectral Interpretation and Applications Interpretation of Mass Spectra: Structural Determination of Simple Molecules Mass Spectral Interpretation: Some Examples Applications of Molecular MS Atomic MS Problems Appendix Bibliography Principles of Chromatography Introduction to Chromatography What is the Chromatographic Process? Chromatography in More than One Dimension Visualization of the Chromatographic Process at the Molecular Level: Analogy to "People on a Moving Belt Slideway" Digression on the Central Role of Silicon-Oxygen Compounds in Chromatography Basic Equations Describing Chromatographic Separations How Do Column Variables Affect Efficiency (Plate Height)? Practical Optimization of Chromatographic Separations Extra-Column Band Broadening Effects Qualitative Chromatography: Analyte Identification Quantitative Measurements in Chromatography Examples of Chromatographic Calculations Problems Bibliography Gas Chromatography Historical Development of GC: The First Chromatographic Instrumentation Advances in GC Leading to Present-Day Instrumentation GC Instrument Component Design (Injectors) GC Instrument Component Design (The Column) GC Instrument Operation (Column Dimensions and Elution Values) GC Instrument Operation (Column Temperature and Elution Values) GC Instrument Component Design (Detectors) Hyphenated GC Techniques (GC-MS, GC-IR, GC-GC, or D-GC) Retention Indices (A Generalization of Relative Rt Information) Scope of GC Analyses Problems Appendix 12.1 Bibliography Chromatography with Liquid Mobile Phases High-Performance Liquid Chromatography Chromatography of Ions Dissolved in Liquids Affinity Chromatography Size-Exclusion Chromatography Supercritical Fluid Chromatography Electrophoresis Planar Chromatography and Planar Electrophoresis Problems and Exercises Appendix 13.A Bibliography Surface Analysis Introduction Electron Spectroscopy Techniques Ion Scattering Spectroscopy Secondary Ion Mass Spectrometry Electron Microprobe (Electron Probe Microanalysis) Problems Bibliography Electroanalytical Chemistry Fundamentals of Electrochemistry Electrochemical Cells Electroanalytical Methods Liquid Chromatography Detectors Spectroelectrochemistry Quartz Crystal Microbalance Suggested Experiments Problems Appendix 15.A Bibliography Thermal Analysis Thermogravimetry Differential Thermal Analysis Differential Scanning Calorimetry Hyphenated Techniques Thermometric Titrimetry Direct Injection Enthalpimetry Microcalorimetry Thermomechanical Analysis and Dynamic Mechanical Analysis Optical Thermal Analysis Summary Suggested Experiments Problems Bibliography Acronyms Index Index

Szczegóły: Undergraduate Instrumental Analysis - George Frame, Eileen Skelly Frame, James Robinson

Tytuł: Undergraduate Instrumental Analysis
Autor: George Frame, Eileen Skelly Frame, James Robinson
Wydawnictwo: CRC Press Inc.
ISBN: 9781420061352
Rok wydania: 2014
Ilość stron: 1264
Waga: 2.38 kg

Recenzje: Undergraduate Instrumental Analysis - George Frame, Eileen Skelly Frame, James Robinson